This paper analyzes the cause of ammonium sulfate discoloration in Bayuquan Branch of Angang Steel Co.,Ltd..The problems of ammonium sulfate discoloration have been solved effectively by taking the measures,such as slag cleaning from mother liquor tank,standardizing centrifugal operation,strengthening pickling water operation,improving the quality of sulfuric acid and lowering the temperature on top of ammonia stripper,etc..