燃料与化工 ›› 2011, Vol. 42 ›› Issue (4): 1-4.

• 综述与专论 •    下一篇

典型无烟煤热解成分的定量分析研究

孙绍增1   曾 光2    魏 来2    赵志强2   钱 娟1   

  1. 1.哈尔滨工业大学能源科学与工程学院,哈尔滨 150001;  2.东北电力科学研究院调整实验研究所,沈阳 110006
  • 出版日期:2011-07-30

Quantitative analysis and study on pyrolysis component of typical anthracite

Sun Shaozeng1     Zeng Guang2     Wei  Lai2       Zhao  Zhiqiang2     Qian Juan1   

  1. 1. Harbin Institute of Technology, Harbin 150001, China;
    2.Commissioning & Test Department, Northeast Electric Power Research Institute, Shenyang 110006, China

  • Online:2011-07-30

摘要:

采用TG-FTIR联用对3种无烟煤的热解产物中的CH4、CO、CO2、NH3进行定量分析研究。结果表明,随着挥发分含量的减少,CH4开始析出温度和析出峰值温度逐渐升高;各煤样的CO析出峰值温度接近一致;CO2的开始析出温度均在195℃左右,CO2的析出总量随煤样的挥发分的升高而增加;NH3的温度析出规律相似,但煤样的NH3析出在900℃时反应并未彻底,挥发分和氮含量均最高的焦作煤样NH3析出量最大,龙岩煤最小。 

Abstract:

CH4, CO, CO2 and NH3 in pyrolysis products of three kinds of anthracites were quantitatively analyzed and studied by means of TG-FTIR. The result showed that the start release temperature and release peak temperature of CH4 were gradually increased together with the reduction of the volatile matter content; CO release peak temperature of individual coal sample was basically the same. the start release temperature of CO2 was about 195℃, the release total amount of CO2 was increased with the increase of the volatile mat ters of coal sample, the temperature release law of NH3 was similar, but the release of NH3 of coal sample at 900℃ was not thoroughly reacted, the NH3 release amount of coal sample from Jiaozuo which has maximum volatile matter and nitrogen content was maximum, however, Longyan coal was minimum.

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