添加过渡金属对低碳MgO-C耐材性能的影响

耐火与石灰 ›› 2020, Vol. 45 ›› Issue (5): 14-17.

添加过渡金属对低碳MgO-C耐材性能的影响

卢咏明陈海山张小红程峰崔任渠

瑞泰马钢新材料科技有限公司，马鞍山243000

出版日期:2020-10-10 发布日期:2020-10-16

Effect of transition metal addition on properties of low carbon MgO-C refractories

Lu Yongming Chen Haishan Zhang Xiaohong Cheng Feng Cui Renqu

Ruitai Masteel New Material Technology Co.,Ltd., Ma’anshan 243000, China

Online:2020-10-10 Published:2020-10-16

摘要/Abstract

摘要：

研究了添加过渡金属Fe粉、Ni粉对低碳MgO-C耐材在不同热处理温度下的显微结构影响。结果表明：添加Fe粉和Ni粉有利于促进无定形炭向结晶碳转变，且热处理温度的提高有利于结晶碳和尖晶石的生成。当热处理温度高于1 200 ℃时，试样中生成了碳纳米管和高温陶瓷相MgAl2O4晶须，有助于提高低碳MgO-C耐材的力学性能和热震稳定性。

关键词: 低碳MgO-C耐材, 碳纳米管, 晶须, 过渡金属, 力学性能, 热震稳定性

Abstract:

The effects of transition metal Fe powder and Ni powder on the microstructure of low carbon MgO-C refractories at different heat treatment temperatures were studied.The results showed that the addition of Fe powder and Ni powder is beneficial to the transition from amorphous carbon to crystalline carbon,and the increase of heat treatment temperature is beneficial to the formation of crystalline carbon and spinel. Carbon nanotubes and high temperature ceramic MgAl2O4 whisker were obtained when the heat treatment temperature was higher than 1 200 ℃,which is helpful to improve the mechanical properties and thermal shock resistance of low carbon MgO-C refractories.

Key words:

"> Low carbon MgO-C refractories, Carbon nanotubes, Whisker, Transition metal, , Mechanical property, Thermal shock resistance

中图分类号:

TQ175.714

卢咏明陈海山张小红程峰崔任渠. 添加过渡金属对低碳MgO-C耐材性能的影响[J]. 耐火与石灰, 2020, 45(5): 14-17.

Lu Yongming Chen Haishan Zhang Xiaohong Cheng Feng Cui Renqu.

Effect of transition metal addition on properties of low carbon MgO-C refractories

[J]. REFRACTORIES & LIME, 2020, 45(5): 14-17.

[1]	马金力　苏　鑫　李凤友　石艳茹. AOD 精炼炉炉底用镁钙质捣打料的研发与应用[J]. 耐火与石灰, 2023, 48(6): 38-39.
[2]	林梓萌　杨　健　尹卓臣２　赫丽杰　孔德高　王知攀１. 粉煤灰加入对水泥基泡沫保温板性能的影响 [J]. 耐火与石灰, 2023, 48(5): 6-9.
[3]	邵荣丹　何见林　丛培源　夏昌勇. 抗氧化剂对 Al2O3-SiC-C 铁沟浇注料性能的影响[J]. 耐火与石灰, 2023, 48(5): 20-25.
[4]	徐华伟　杨政宏　金丛进　张品为　张兴华　节　闯. 氧化镁晶须在镁质材料表界面的生长机制[J]. 耐火与石灰, 2023, 48(5): 29-33.
[5]	朱宇轩刘浩王周福马妍王玺堂陈少一. 氧化镧对方镁石-镁橄榄石质耐火材料结构与性能的影响[J]. 耐火与石灰, 2022, 47(3): 11-15.
[6]	赵会敏薛娟娟. 含纳米TiO2高铝浇注料微观结构和力学性能的研究[J]. 耐火与石灰, 2021, 46(3): 44-53.
[7]	卢咏明张小红陈海山崔任渠. 低碳镁碳砖热解产物的分析研究[J]. 耐火与石灰, 2021, 46(2): 18-21.
[8]	薛娟娟孙凯赵会敏王斌. 一种新型磁性铝基纳米复合材料的研制[J]. 耐火与石灰, 2021, 46(1): 55-60.
[9]	王晓阳. 采用溶胶浸渍造孔剂法制备性能优良的多孔氧化铝陶瓷[J]. 耐火与石灰, 2020, 45(1): 46-48.
[10]	王少阳罗旭东. 采用溶胶浸渍造孔剂法制备性能优良的多孔氧化铝陶瓷[J]. 耐火与石灰, 2020, 45(1): 49-53.
[11]	王晓阳. 使用CaO-Al2O3-SiO2-MgO微滴为催化剂促进MgO晶须生长[J]. 耐火与石灰, 2019, 44(6): 53-57.
[12]	魏博. 添加不同形状不锈钢纤维的浇注料的力学性能[J]. 耐火与石灰, 2019, 44(2): 46-47.
[13]	梁媛媛. Al2O3晶须强化细晶氧化铝陶瓷的放电等离子烧结研究[J]. 耐火与石灰, 2018, 43(3): 45-50.
[14]	王晓阳. CNT添加剂对MgO-C耐火材料的影响[J]. 耐火与石灰, 2018, 43(3): 37-41.
[15]	徐勇. 高岭土基陶瓷的气孔率和力学一致性的影响[J]. 耐火与石灰, 2018, 43(2): 55-62.